Protective Coatings

Protective coatings are the most commonly used method of corrosion control. Protective coatings can be metallic, such as the galvanized steel shown below, or they can be applied as a liquid “paint.” Most of the research and testing of protective coatings at the Kennedy Space Center is related to paint-like protective coatings.

Galvanized and Weathering Steel

Air Conditioner Showing Rust Stains Aluminum Airplan Wing
(Courtesy of www.corrosion-doctors.org)

Filiform corrosion occurs underneath protective coatings. The air conditioner on the left is starting to show rust stains due to problems with protective coating. The same types of problems are starting to appear on the aluminum airplane wing shown on the right.

Source: http://corrosion.ksc.nasa.gov/microbial.htm

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Materials Selection

Materials Selection

Weathering Steel StatueMost large metal structures are made from carbon steel-the world’s most useful structural material. Carbon steel is inexpensive, readily available in a variety of forms, and can be machined, welded, and formed into many shapes.

This large statue by Pablo Picasso in front of the Chicago city hall is made from a special form of carbon steel known as weathering steel. Weathering steel does not need painting in many boldly exposed environments. Unfortunately, weathering steel has been misused in many circumstances where it could not drain and form a protective rust film. This has given the alloy a mixed reputation in the construction industry.

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Hydrogen Damage

Hydrogen can cause a number of corrosion problems. Hydrogen embrittlement is a problem with high-strength steels, titanium, and some other metals. Control is by eliminating hydrogen from the environment or by the use of resistant alloys.

Hydrogen blistering can occur when hydrogen enters steel as a result of the reduction reaction on a metal cathode. Single-atom nacent hydrogen atoms then diffuse through the metal until they meet with another atom, usually at inclusions or defects in the metal. The resultant diatomic hydrogen molecules are then too big to migrate and become trapped. Eventually a gas blister builds up and may split the metal as shown in the picture below.

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Galvanic Corrosion

Galvanic Corrosion Galvanic corrosion is an electrochemical action of two dissimilar metals in the presence of an electrolyte and an electron conductive path. It occurs when dissimilar metals are in contact. It is recognizable by the presence of a buildup of corrosion at the joint between the dissimilar metals. For example, when aluminum alloys or magnesium alloys are in contact with steel (carbon steel or stainless steel), galvanic corrosion can occur and accelerate the corrosion of the aluminum or magnesium. This can be seen on the photo above where the aluminum helicopter blade has corroded near where it was in contact with a steel counterbalance.

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Why Metals Corrode ?

Metals corrode because we use them in environments where they are chemically unstable. Only copper and the precious metals (gold, silver, platinum, etc.) are found in nature in their metallic state. All other metals, to include iron-the metal most commonly used-are processed from minerals or ores into metals which are inherently unstable in their environments. This golden statue in Bangkok, Thailand, is made of the only metal which is thermodynamically stable in room temperature air. All other metals are unstable and have a tendency to revert to their more stable mineral forms. Some metals form protective ceramic films (passive films) on their surfaces and these prevent, or slow down, their corrosion process. The woman in the picture below is wearing anodized titanium earrings. The thickness of the titanium oxide on the metal surface refracts the light and causes the rainbow colors on her earrings. Her husband is wearing stainless steel eyeglasses. The passive film that formed on his eyeglasses is only about a dozen atoms thick, but this passive film is so protective that his eyeglasses are protected from corrosion. We can prevent corrosion by using metals that form naturally protective passive films, but these alloys are usually expensive, so we have developed other means of corrosion control.

Anodic Protection

Overview

Anodic Protection is a corrosion mitigation technique first introduced in the 1960′s in which the potential of an alloy is controlled relative to a stable reference potential in a range of values more positive or oxidizing than the corrosion potential that causes the corrosion rate to be depressed relative to that which would occur without the application of the potential. One of the major applications of this technique is the protection of carbon steel or 304 or 316 stainless steel in concentrated (greater than 93 wt%) sulfuric acid. Other applications have been reported in the literature. One excellent though dated reference that provides background on theory and practice is “Anodic Protection”, O. L. Riggs and C. E. Locke, Plenum Press, New York, 1981. Further information can be found in “Corrosion Engineering”, M. G. Fontana, Mc-Graw Hill Book Company, New York, 1986.

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What is MIG Welding?

MIG welding is an abbreviation for Metal Inert Gas Welding. It is a process developed in the 1940’s, and is considered semi-automated. This means that the welder still requires skill, but that the MIG welding machine will continuously keep filling the joint being welded.

MIG welders consist of a handle with a trigger controlling a wire feed, feeding the wire from a spool to the weld joint. The wire is similar to an endless bicycle brake cable. The wire runs through the liner, which also has a gas feeding through the same cable to the point of arc, which protects the weld from the air.

MIG welding is most commonly used in fabrication shops where production is high, and the possibility of wind blowing away your gas shielding is unlikely.

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Bacterial Corrosion in Ships’ Tanks Problem and Solution

 FACT OR MYTH?

“Small animals eating steel” is a myth. It is however a fact that local corrosion, occurring at very high rates and typically looking like clusters of pits, can be caused by chemical processes initiated by bacterial activity, i.e. bacterial corrosion exists. This phenomenon is sometimes described as “microbial corrosion” indicating that types of microbes other than bacteria may be involved in the process. The accepted technical term is “microbially influenced corrosion”. Bacterial corrosion most frequently occurs on cargo oil tank bottom plating. It occurs also in water ballast tanks, primarily on up-facing, horizontal surfaces.

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Advantages of an “Expansion Joint” versus a “Pipe Loop”

By David Smith & John Demusz

An expansion joint and a pipe loop are two methods employed to safely absorb thermal expansion or contraction in piping systems due to thermal temperature changes. When design conditions exist, where an expansion joint or a pipe loop can be utilized, the major advantages of using an expansion joint are as follows:

  1. Space is inadequate for a pipe loop with sufficient flexibility.
  2. A minimum pressure drop throughout the pipe line is required and the absence of flow turbulence from the elbows and piping is required by process flow conditions.

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What Is a Seismic Survey?

A seismic survey is used to investigate Earth’s subterranean structure and is mainly used for oil and gas exploration. This method uses the principles of reflective seismology to acquire and interpret seismic data, which permits the estimation of the Earth’s composition. The technique is similar to that used by computerized axial tomography (CAT) scans, involving the analysis of seismic waves that travel through the Earth.

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